The devil may wear Prada, but Emily Blunt is rocking Valentino at the 2023 Oscars.

The Mary Poppins Returns star was dressed to the nines for movie's biggest night on March 12. Arriving to the Dolby Theatre in Los Angeles, Emily stunned in a white, off-shoulder gown from the luxury fashion label. In a true fashionista move, the actress completed her look with pink diamond chandelier earrings by Chopard, Alexandre Birman shoes and a studded clutch. (See all the red carpet fashions here.)

Emily, whose hair was styled by Laini Reeves using John Frieda products, was joined by her Jungle Cruise co-star Dwayne Johnson on the red carpet. The two are slated to present at the star-studded ceremony, where the likes of fellow presenters Ariana DeBose, Michael B. Jordan, Janelle Monáe, Riz Ahmed, Jennifer Connelly, Samuel L. Jackson, Troy Kotsur and Jonathan Majors will also take the stage.

The actress' Oscars outing weeks after she and husband John Krasinski—with whom she share daughters Hazel, 9, and Violet, 7—enjoyed a parents' night out at the 2023 SAG Awards. In addition to presenting at the Screen Actors Guild gathering, the actress was nominated for Outstanding Performance by a Female Actor in TV Movie or Limited Series, but lost the Actor trophy to Jessica Chastain.

This year's competition at the Academy Awards is fierce—with Everything Everywhere All at Once coming into the award show with 11 nominations, including acting nods for Michelle Yeoh, Ke Huy Quan, Jamie Lee Curtis and Stephanie Hsu. (Check out the complete list of nominees here.)

But before Emily hands out an Oscar, check out all the stars on the red carpet below.

In Elie Saab Couture with Bulgari jewelry

In Moschino

In Gucci

In Vera Wang

In Dolce & Gabbana

In Alaïa with Moussaieff jewelry 

In Versace with Tiffany & Co. jewelry 

In Christian Siriano

In Louis Vuitton

In Vivienne Westwood with Pomellato jewelry 

In Alexander McQueen with Fred Leighton jewelry 

In Louis Vuitton

In Vera Wang with REZA jewelry

In Valentino with Chopard jewelry 

In Chanel Couture with Tiffany & Co. jewelry

In Louis Vuitton with Tiffany & Co. jewelry 

In Fendi with David Yurman and OMEGA jewelry

In Tamara Ralph with Pomellato jewelry 

In Christian Dior Couture with Moussaieff jewelry 

In Giorgio Armani with OMEGA and Fred Leighton jewelry 

In Armani Privé with OMEGA jewelry

In Dolce & Gabbana with Tag Heuer jewelry 

In LaQuan Smith

In Gucci

In Rodarte with Chopard jewelry 

In Dolce & Gabbana

In Gucci

Check out E! News' Oscars blog for a full recap of the 2023 Academy Awards.